Create Order
Go to Salesforce Org - Apps - Orders
Click New button on Salesforce Order page
Fill all necessary fields on New Order: Magento Order page
Click Save button and check new order was created in Salesforce
Click Add Product button on the Related - Order Products section
Select Pricebook assigned to Main Magento website and click Save button
Select some product and click Next
Add Quantity and click Save
Click Update Status in Magento - Send data to Magento button
go to Salesforce Magento queue and check new order record in Success status
go to Magento Admin panel - Sales - Orders - Edit order
New Order was created in Magento